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Croconate violet : ウィキペディア英語版
Croconate violet

Croconate violet or 1,3-bis(dicyanomethylene)croconate is a divalent anion with chemical formula or ((N≡C-)2C=)2(C5O3)2−. It is one of the pseudo-oxocarbon anions, as it can be described as a derivative of the croconate oxocarbon anion through the replacement of two oxygen atoms by dicyanomethylene groups =C(-C≡N)2. Its systematic name is 3,5-bis(dicyanomethylene)-1,2,4-trionate. The term croconate violet as a dye name specifically refers to the dipotassium salt .
==History and synthesis==
The anion was synthesized and characterized by A. Fatiadi in 1978. He obtained the potassium salt by treating dipotassium croconate with malononitrile in water solution at 80–90 °C.〔
Alexander J. Fatiadi (1978), ''Synthesis of 1,3-(dicyanomethylene)croconate salts. New bond-delocalized dianion, "Croconate Violet"''. Journal of the American Chemical Society, volume 100 issue 8, pages 2586–2587.
〕 The dipotassium salt crystallizes from water as a dihydrate in deep blue metallic needles. The water solutions have an intense violet color and strongly stain the skin.〔

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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